This is where basf plastic additives customer specific blends csb steps in to provide a complete stabilization package, tailored to customers needs, based on extruded or compacted mixtures of irganox and irgafos. Liquid antiscorch package for polyols, bht free, low amine. Irganox b 215 ff c msds download sevron safety software. Irganox 565 is a highly effective antioxidant for a variety of elastomers including polybutadiene, polyisoprene, emulsion styrene.
Irganox 1076 mw 530 tdgcms irganox 1010 mw 1178 identical methyl derivative is formed from irganox 1010 and irganox 1076 fig. Detection of the additive irganox 1076 in polyethylen. Auxiliary antioxidant, which synonym name is a secondary antioxidant, react with hydroperoxides to produce nonradical products and are therefore often termed hydroperoxide decomposers. Irgafos 168 comprised in phenol free systems with other appropriate basf stabilizers addresses specific stabilization requirements.
Irganox properties palatinol 10p stab irganox is a nearly colorless, clear and practically anhydrous liquid with a hardly noticeable odor. Basfs finished lubricants ensure firstclass results in terms of gear wear, seal life, fluid oxidation and oil life. Antioxidant 4720, antioxidant 1076, antioxidant b215 and so on, we promise will offer the best price by the good quality in china. Induction period values of pe stabilized with various antioxidants for oxidations performed under air at 200c i0 8 0. Provides excellent processing and longterm thermal stability as well as excellent initial resin color. Contaminated water and soil must be disposed of in conformity with local regulations. Irganox 1076 octadecyl 3,5ditertbutyl 4hydroxyhydrocinnamate 0 33. Concentration levels of irganox 1076 in hot melt adhesives range from 0. Bnx 565 is a highly effective antioxidant for unsaturated elastomers such as polybutadiene, polyisoprene. These molecules have unique mws, though, and can be analyzed using selective ms detection. The samples will be separated by reverse phase chromatography on a waters tm novapakc18 column 2mm x 150mm using the following liquid chromatographic conditions. The reactants were mixed at room temperature, using manual stirring.
Bnx 565 991844 is a high molecular weight, non staining, multifunctional antioxidant developed for the stabilization of. Determination of antioxidants irganox 1076 and irganox. Irganox 1076 especial offers effective protection against overbake yellowing by terminating free radicals. The polymer processing industry requires additives in an easytohandle, free flowing and lowdust product form. Using the standard addition method, the concentrations of irganox 1076 and irganox 1010 were respectively determined to be 374 ppm 10% error and 429 ppm 9% error. Basf irganox 565 triiso tryline is not authorized by basf to post safety data sheets sds for basf irganox 565 on our website. Dilts,waters chromatography,milfordma, 01757 introduction. The synthetic lubricants also provide sustainability benefits, for example, by helping to improve energy efficiency which reduces fuel consumption and decreases co 2 emissions. Jan 25, 2020 irganox 3114 pdf get instant access to irganox technical datasheet.
Journal of applied polymer science 1986, 31 6, 17091719. Structure, properties, spectra, suppliers and links for. Irganox ensures longterm thermal and process stability in a wide variety of applications. Irganox 1076 is recommended for styrene homo and copolymers at a concentration level ranging from 0. M 6196 e february 2015 page 2 of 3 palatinol 10p stab. Evernox 565 is a direct dropin replacement for irganox 565 same cas number.
Irganox 1098 irganox 1098 by basf is a n,nhexane1,6diylbis33,5ditertbutyl4hydroxyphenylpropionamide. Gas chromatographic determination of acidcatalyzed transesterified antioxidant additive irganox 1076 in polypropylene. Irgafos 168 comprised in phenol free systems with other appropriate basf stabilizers. It is a multifunctional phenolic antioxidant compatible with several polymers used in adhesives such as.
Chromatogram of pe with irganox 1076 obtained by thermal desorption. Irganox 565 has low volatility, prevents gel formation, changes to molecular weight and maintains excellent polymer color. Antioxidants work to slow down the oxidation cycle, usually by scavenging free radicals. Irganox and irgafos antioxidants ao protect coatings, plastics, fibers. In particular, irganox 565 is an antioxidant used as a processing stabilizer in the manufacture of. Extensive performance data of irganox 1076 in various organic polymers and. The hindered phenols additionally provide storage stability and give the polymer long term protection against thermooxidative degradation. Oxidative stability of irradiated uhmwpe stabilized with. Det visades att losligheten av irganox 565 i pdms var lagre an losligheten av var och.
Irganox 565 is approved in many countries for use in food contact applications. Autoxidation may be initiated by heat, high energy radiation such as ultraviolet light, mechanical stress, or through reaction with other impurities. Irganox 1010, irganox 1076, irganox 1098, irganox 30, irganox 1425 wl, irganox 3114, irganox 245 and irganox 15 are primary antioxidants. Irganox 1010 irganox 565 ethanox 330 irganox 1076 irgafos 168 figure 2. Primary antioxidantsfreeradical scavengers hindered phenols. Irganox 1076, a sterically hindered phenolic antioxidant, is a highly efficient. The oxidation of ultrahigh molecular weight polyethylene. Thermal protection and processing stability for plastics.
Some additives are designed to react and transform polyolefin sheet bht and irganox 1076 undergo similar chemical transformations. The chemical market in china is by far the largest in the world and will make up twothirds of the total growth of the global chemical market over the next five years. Characterization of additives at polymer surfaces by tof. Bnx 565 is a high molecular weight, nonstaining, multifunctional antioxidant developed for the stabilization of unsaturated elastomers br, ir, sbr, sis, sbs, etc. It is listed in aics, dsl, china, einecs, miti, ecl, piccs and tsca. Get instant access to irganox 565 technical datasheet. Process and thermal stabilizers for specialty polymers. Cch 3 3 oh ch 2 ch 2 cooc 18 h 37 ch 3 3 c figure 1. Identification of polymer additives by liquid chromatography. Sufficient measures must be taken to retain water used for extinguishing.
Irganox 1010 p, ff 1178 110 125 n n n n n n n n n n n o o high molecular weight, phenolic antioxidant ao. Evernox 565 is a hindered phenolic antioxidant based on 2,6ditertbutyl44,6bisoctylthio1,3,5triazin2ylaminophenol. Your account will serve as your personal sds inventory, which you can access from anywhere, 247 to search for any safety data sheets you need in the future. It is a high molecular weight, nonstaining, antioxidant for processing and longterm thermal. Antioxidants to prevent polymer oxidation polymer additives. Bnx 565 991844 is a high molecular weight, nonstaining, multifunctional antioxidant developed for the stabilization of. Extensive performance data of irganox 1010 in various organic polymers and applications are available upon request. Sims article pdf available in surface and interface analysis 341. Irganox 30 irganox 1076 tri tbu phenol cyanox 1790 pure pe figure 4. Free radical scavengers primary antioxidants free radical scavengers hindered phenols.
Bnx 565 is also useful for the stabilization of hot melt adhesives especially those derived from unsaturated elastomers and rosin ester tackifier resins. Irganox 1010, magnified 200x secondary aromatic amines are primary antioxidants mainly used in carbonblack filled rubbers and some polyurethane applications. Identification of polymer additives by liquid chromatographymass spectrometry article in polymer degradation and stability 9112. Irganox 565 by basf is a 2,6ditertbutyl44,6bisoctylthio1,3,5triazin2ylamino phenol. Renewable content and high biodegradability make a range of basfs finished lubricants. Used for polyethylene power cables, xlpe power cables, hdpe pipe, polypropylene, polyolefin underhood automotive applications, styrene homo and copolymers. They differ from primary phenols and amines in that they are decomposed by reaction with the hydroperoxide, rather than containing it. Irganox ps 800 by basf is a heat stabilizer in combination with a thioester antioxidant. Special protective equipment for firefighters wear full protective clothing. Sample of pure irganox 1076, pyrolysis temperature 764 c, pyrolysis time. Irganox 565 basf adhesives ingredients specialchem. Irganox comprises the broadest range of antioxidants for the use in organic substrates such as plastics, synthetic fibers and elastomers. Bnx 565 is a highly effective antioxidant for unsaturated elastomers such as polybutadiene, polyisoprene, styrenebutadiene rubber, and styrenic block copolymers such as sis and sbs.
Pdf characterization of additives at polymer surfaces by. Screening and qualitative identification of antioxidant. It is a multifunctional phenolic antioxidant compatible with several polymers used in adhesives such as hot melt, solventbased. Determination of bht, irganox 1076, and irganox 1010. Massachusetts general hospital, harris orthopedic laboratory, boston, ma. Determination of antioxidants irganox 1076 and irganox 1010. Besides,antioxidant 565 is also a high molecular weight,nonstaining,multifunctional antioxidant for the stabilization of unsaturated elastomers such as br,ir,sbr,sis,sbs etc,hot melt adhesive. Concentration levels of irganox 1010 in hot melt adhesives range from 0. It is a sterically hindered phenolic antioxidant which protects against thermooxidative degradation. Antioxidants are additives which prevent the degradation of plastics, lubricants and coatings. It is soluble in the usual organic solvents and is miscible and compatible with all of the monomeric plasticizers commonly used in pvc. It is a high molecular weight, nonstaining, antioxidant for processing and longterm thermal stabilization. Irganox 565 is a synthetic organic chemical used as an antioxidantcatalyst. Study the material safety data sheets for the hazards of the chemical, learn the instructions on handling, storage and the emergency measures in case of accident take our free online course to learn how to to properly apply and use your msds complete a full risk assessment for your workplace so that you can map out all the hazards into a single comprehensive coshh assessment.
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