Coniferyl alcohol an overview sciencedirect topics. It participates in the initial stages in the biosynthesis of lignin. Sinapyl alcohol is a precursor to lignin or lignans. Buy sinapyl alcohol cas 537337, a biochemical for proteomics research, from santa cruz. Wear selfcontained, approved breathing apparatus and full protective clothing, including eye protection and boots. The monomers are essentially the same, differing only in the number of methoxyl groups. Adh isoforms used coniferyl and sinapyl alcohol as substrates but with a much. If exposure limit is exceeded, use respiratory protection protective clothing. Sinapyl alcohol is an organic compound derived from cinnamic acid. Ac10770, ac107710010, ac107710025, ac107710200, ac390690000, ac390690010 ac390690010, a4011, a401500, nc9757992, nc9766578, nc9767417, nc9767429 synonyms. Safety data sheet isopropyl rubbing alcohol usp 70% 1. Isopropyl alcohol us osha twa 400 ppm isopropyl alcohol us acgih twa 200 ppm isopropyl alcohol us acgih stel 400 ppm appropriate engineering controls. Packaging 100 mg in clear glass bottle other notes tandem mass spectrometry data independently generated by scripps center for metabolomics is available to view or download in pdf. For large fires, use water spray, fog, or alcohol resistant foam.
Fire fighting measures flammable properties the product is flammable, and heating may generate vapours which may form explosive vapourair mixtures. Intermediate qmbb is a surprisingly stable, isolable product in. For eye contact, flush with running water for at least 15 minutes. Loosen clothing as necessary and position individual in a comfortable position. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye. Here the phylogeny analysis, three dimensional protein model. Sinapyl alcohol cas 537337 scbt santa cruz biotechnology. Crosscoupled product 2ab has been found in actively lignifying xylem tissue in poplar. An appropriate nioshmsha approved respirator is recommended if dust is generated. Material safety data sheet virex ii 256 call medical attendant, doctor, or poison control center immediately. Sinapyl alcohol, a monolignol, is a primary lignin monomer.
Msds material safety data sheet 512 5352711 state of the art ingredients fast friendly service trade name cetearyl alcohol cetostearyl alcohol nf inci name cetearyl alcohol hazard summary as defined by osha hazard communication standard, 29 cfr 1910. Cetyl alcohol cas no 36653824 material safety data sheet sds msds. P202 do not handle until all safety precautions have been read and understood. Benzyl alcohol can extract and dissolve polystyrene plastic and may attack other plastics. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Transgenic poplar, downregulated in cinnamyl alcohol dehydrogenase cad or caffeic. Reagent alcohol, acs safety data sheet according to federal register vol. Sinapyl alcoholspecific peroxidase isoenzyme catalyzes the. Explosion limit propellant butane propane lower explosion limit lel 1. Isopropyl alcohol safety phrases s9 keep container in a wellventilated place. Section e reagent msds material safety data sheet page 1 of 4. Use proper bonding and grounding when transferring material.
Exposure to high concentrations has a narcotic effect, producing symptoms of dizziness, drowsiness, headache, staggering, unconsciousness and possibly death. Hazard identification this product does not contain any hazardous ingredients. Ethanol is rapidly oxidized in the body to acetaldehyde, then to. The protein product of sad gene is responsible for high lignin content which provides benefit in timber industry. Exposure controlspersonal protection aacceptable maximum peak. Sinapyl alcoholspecific peroxidase isoenzyme catalyzes. It is biosynthetized via the phenylpropanoid biochemical pathway, its immediate. Symptoms may include headache, excitement, fatigue, nausea, vomiting, stupor, coma and possible death due to respiratory failure. Do not induce vomiting unless told to do so by a poison control center or doctor. In case of fire, use water spray, dry powder, alcohol resistant foam, or carbon dioxideto extinguish. Exposure controlspersonal protection never use welding or cutting torch on or near containers even empty because product can ignite explosively. Cetyl alcohol material safety data sheet cas no 36653. Oct 21, 2004 preparation and relevance of a crosscoupling product between sinapyl alcohol and sinapyl phydroxybenzoate.
Dispose of contents and container in accordance with local, regional, national, and international regulations. Article pdf available in current enzyme inhibition 16 january 2020 with 38 reads. This msds was prepared and is to be used only for this product. Do not handle until all safety precautions have been read and understood. Lignin sulfonate has the chemical formula c 20 h 26 o 10 s 2 nlm, 20b and its structure is presented 51 in figure 1. Store in a cool, dry, wellventilated area away from incompatible substances. Sinapyl alcohol may be employed in the preparation of lignin, a highly stable biopolymer. This phytochemical is one of the monolignols, which are precursor to lignin or lignans. Purification and characterization of cinnamyl alcohol. Cetostearyl alcohol extra pure msds cas 67762305 msds.
Most important symptoms and effects, both acute and delayed harmful if swallowed. Pdf inhibition by substrates of a coniferyl alcohol dehydrogenase. The lignin framework is a sulfonated random polymer of three aromatic alcohols. It has been evaluated for antiinflammatory and antinociceptive activities. Material safety data sheet 3 health hazard data potential health effects. It is biosynthetized via the phenylpropanoid biochemical pathway, its immediate precursor being sinapaldehyde. Identification product identifier isooctyl alcohol other means of identification product code ng16855 recommended use for laboratory use only recommended restrictions none known. Keep cool p405 store locked up p501 dispose of contentscontainer to comply with local, state and federal regulations. Provide exhaust ventilation or other engineering controls t o keep the airborne concentrations of vapors below their respective threshold limit value. In softwoods, coniferyl alcohol is the dominant monomer 94% coniferyl, 1% sinapyl, 5% coumaryl alcohols. Safety data sheet according to federal register vol.
Sinapyl alcohol is an organic compound structurally related to cinnamic acid. The halflife for ethanol in the atmosphere is one to ten days. Firstaid measures eyes in case of eye contact, rinse with plenty of water and seek medical attention. Identification of the substancemixture and of the companyundertaking 1. Safety data sheet isopropyl alcohol 20% revision date 61515 1. Isopropyl alcohol 2propanol safety data sheet according to federal register vol. It is also a biosynthetic precursor to various stilbenoids and coumarins.
However, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Risk of explosion theoretically a risk of explosion exists with the use of butane and propane as propellants for ballistol aerosols. Material safety data sheet isopropyl alcohol, 50 2 ingestion. Structural and kinetic basis for substrate selectivity in. Diacetone alcohol material safety data sheet cas no.
Lignin is a complex biopolymer composed of different amounts of three monolignols, namely pcoumarylalcohol, coniferyl alcohol, and sinapyl alcohol doherty et al. Have person sip a glass of water if able to swallow. Product name sinapyl alcohol product code sc236884 recommended use of the chemical and restrictions on use for research use only. Accidental release measures remove all sources of flame, sparks and heat.
Material safety data sheet reagent alcohol denatured ethanol. Firefighting measures promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. The three phenylpropylene lignin monomers transconiferyl alcohol, trans sinapyl alcohol and transpcoumaryl alcohol are shown in figure 1. Sinapyl alcohol specific peroxidase isoenzyme catalyzes the formation of the dehydrogenative polymer from sinapyl alcohol received. Modifications in lignin and accumulation of phenolic glucosides in. All chemicals may pose unknown hazards and should be used with caution. The addition of ethyl ferulate, methyl pcoumarate, or sinapyl pcoumarate conjugates to a reaction mixture containing peroxidase, sinapyl alcohol, and hydrogen peroxide stimulated the rate of sinapyl alcohol radical coupling by 1020fold. Handling and storage keep containers away from heat, and out of the reach of small children. Inhalation inhalation of vapors irritates the respiratory tract. Safety data sheet cetostearyl alcohol msds catalog service llc. Approximately 25% of individuals show signs of intoxication at these levels.
Firstaid measures description of first aid measures call a physician or poison control centre immediately. December 26, 2001 abstract two peroxidases, cwpoa and cwpoc, were isolated from the cell walls of. Extreme high moderate low section 1 chemical product and company identification product name sinapyl alcohol statement of hazardous nature not considered a hazardous substance according to osha 29 cfr 1910. Definition calcium lignosulfonate 40 65 is an amorphous material obtained from the sulfite pulping of softwood. Never give anything by mouth to an unconscious person. Preparation and relevance of a crosscoupling product between. Our msds database is an easy to use, do it yourself tool, and best of all. Disposal considerations any disposal practice must be in compliance with local, state, and federal laws and regulations contact local or state government agency for specific rules. Reagent alcohol, 100% safety data sheet according to federal register vol. Coupling reactions of sinapyl alcohol and sinapyl phydroxybenzoate has been reported.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. This was challenged by the discovery of a novel sinapyl alcohol. In human, intake of a large amount of alcohol can cause injury in almost all organs, of which the liver is a target organ that might be adversely effected most. In the presence of iron salts, thermal decompositon can occur, whicn in some cases can become explosive. These propylphenol derivatives, which can be differentiated by their number of methoxy groups, include polar, hydroxyl, and carboxyl groups, which lead to the hydrophilic behavior in lignin figure 7. Isopropyl alcohol 70% issue date april 4 th, 2014 the product has been classified in accordance with the hazard criteria of the controlled products regulations and the msds contains all the information required by the controlled products regulations. Ensure that eye wash stations and safety showers are proximal to the workstation location. Material safety data sheet page 2 of 5 msds cetyl stearyl alcohol nf section 6 accidental release measures personal precautions. Softwood lignins yielded guaiacyl derivatives, coniferaldehyde, and coniferyl alcohol as the major products. S26 in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Calcium lignosulfonate 40 65 page 5 of 8 amounts of lowmolecular weight polymeric material and reducing sugars than does the fccspecified material.
Effect of an excess of both coniferyl alcohol a,b or sinapyl alcohol c, d on. A potential role for sinapyl pcoumarate as a radical. Section 6 accidental release measures general information. Manual integration of the corresponding chromatogram peak followed by a.
However, the actual risk is quite negligible, as the following information illustrates. Ethanol evaporates quickly and is not expected to bioaccumulate. Recommendation for sinapyl alcohol flavor usage levels up to. Mild alcohol intoxication occurs at blood levels between 0. If data for a hazard are not included in this document there is no known information at this time. Absorb spilled material with a nonflammable absorbent such as vermiculite. However, lignin sulfonate may be composed of a variety of sulfonated aromatic alcohols 52 which make up lignin polymers, including pcoumaryl alcohol, sinapyl alcohol, and coniferyl alcohol 53 fao, 2008. India veritas house, 70 mint road, fort, mumbai 400 001. The information in this msds was obtained from current and reliable sources. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this msds. Material safety data sheet lauryl alcohol ethoxylate 2 mol december 1, 2009 page 5 of 5 additional information product may contain trace amounts of ethylene oxide alcohol 2a or comsol 2a2 sds revision date mmddyyyy. If vomiting occurs spontaneously, keep victims head lowered forward to reduce the risk of aspiration.
General room or local exhaust ventilation is usually required to meet exposure limits. Skin contact wash off immediately with plenty of water for at least 15 minutes. Electrical equipment should be grounded and conform to applicable electrical code. Material safety data sheet page 3 of 4 air borne exposure limit. Commission regulation eu no 2015830 of 28 may 2015. This material safety data sheet msds applies only to the material as packaged. Material safety data sheet reagent alcohol denatured ethanol 2 ingestion. During fire, gases hazardous to health may be formed. If this material is part of a multiple component system, read the material safety data sheets for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Syringyl lignin is unaltered by severe sinapyl alcohol.
Special protective equipment and precautions for firefighters. Exposure controlspersonal protection engineering controls. For small fires, use dry chemical, carbon dioxide, water spray or alcohol resistant foam. First aid measures description of first aid measures after inhalation. Identification of the substancemixture and of the companyundertaking. Pfizer inc believes that the information contained in this material safety data sheet is accurate, and while it is provided in good faith, it is without warranty of any kind, expressed or implied. Search results for sinapyl alcohol at sigmaaldrich. It shall be the users responsibility to develop proper. The material is removed from the air by dry and liquid adsorption.
Material safety data sheet sinapyl alcohol sc236884 hazard alert code key. Material safety data sheet isopropanol section 1 chemical product and company identification msds name. Sinapyl alcohol 1a radical 88coupling produces an intermediate bisquinone methide qmaa, scheme 1, which scheme 1 coupling reactions of sinapyl alcohol 1a and sinapyl phydroxybenzoate 1b. Product identifier product name pcoumaryl alcohol product number fc145653 cas number 3690059 ec number 6093085 1. Inhalation move casualty to fresh air and keep at rest. Silikroilaerosol 1102020 sil page 3 of 7 section 8. Do not dump into sewers, any body of water, or onto the ground. Denatured alcohol safety data sheet supercedes revision. Symptoms will vary with alcohol level of the blood.
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